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Synthetic strategies for substituted benzenes (3)

Organic chemistry: Strategies for synthesizing substituted benzenes using electrophilic aromatic substitutions--interconversion of nitro and amino substituents; interconversion of alkanoyl and alkyl substituents, Clemmensen reduction, disadvantages of Friedel-Crafts alkylation (rearrangements and overalkylation); reversible sulfonation as a blocking procedure; moderating the activating power of amino and hydroxy substituents. Arenediazonium salts; Sandmeyer reactions; synthesis of phenol from an arenediazonium salt. Phenyl vs. benzyl; oxidation of benzylic carbons to carboxylic acids with hot potassium permanganate (KMnO4) This is a recording of a tutoring session, posted with the students' permission. These videos are offered on a "pay-what-you-like" basis. You can pay for the use of the videos at my website: http://www.freelance-teacher.com/videos.htm For a list of all the available video series, arranged in suggested viewing order, go to my website. For a playlist containing all the videos in this series, click here: http://www.youtube.com/watch?v=N9OTMeaPaQk&feature=PlayList&p=74B0BD05E526FEF5&index=0&playnext=1 (1) Interconversion of nitro and amino substituents (2) Continued. Interconversion of alkanoyl and alkyl substituents; Clemmensen reduction (3) Continued. Disadvantages of Friedel-Crafts alkylation—rearrangements and overalkylation (4) Continued. Reversible sulfonation as a blocking procedure (5) Continued (6) Moderating the activating power of amino substituents (7) Continued (8) Moderating the activating power of hydroxy substituents (9) Arenediazonium salts; Sandmeyer reaction (10) Continued (11) Continued. Synthesis of phenol from an arenediazonium salt. Phenyl vs. benzyl; oxidation of benzylic carbons to carboxylic acids with hot potassium permanganate (KMnO4) (12) Continued
Length: 10:12

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